Valorization of pressmud waste through hydrothermal treatment for energy conversion and liquid organic fertilizer development

Authors

  • Asroful Abidin Universitas Muhammadiyah Jember
  • Wiyono Apri Universitas Pendidikan Indonesia
  • Fitriana Dina Rizkina Ehime University
  • Danang Kumara Hadi Ibaraki University

Keywords:

hydrothermal treatment, pressmud, potassium, phosphate, hydrochar

Abstract

Pressmud, a by-product of the sugar industry, contains significant amounts of potassium (K) and phosphate (P) but remains underutilized, leading to waste management and environmental concerns. This study investigates the potential of hydrothermal treatment (HT) to enhance the solubility of K and P for pressmud while assessing its influence on the energy characteristics of the resulting hydrochar. HT was conducted at 180oC, 200oC, and 220oC under non-catalytic and zeolite-catalyzed conditions. The liquid fraction was analyzed for K and P concentrations using a photometer, while the hydrochar was evaluated for calorific value and proximate composition. The optimum treatment condition was achieved at 220oC without zeolite, yielding the highest K and P solubilities of 1200 ppm and 1790 ppm, respectively. The presence of zeolite decreased solubility due to its ability to adsorb nutrients. Higher nutrient concentrations were positively correlated with increased calorific value and fixed carbon content, with a maximum value of 2047.56 cal/g. These findings demonstrate that hydrothermal treatment is an effective strategy for nutrient recovery and energy enhancement from pressmud waste, supporting its valorization toward renewable energy production and sustainable fertilizer development.

References

Triono Bambang Irawan, Satria Indra Kusuma, Anni Nur Aisyah, Liliek Dwi Soelaksini, Irma Harlianingtyas, “Penerapan Pupuk Organik Blotong Untuk Meningkatkan Kesuburan Tanah Pada Lahan Tebu di PG. Pradjekan PT. Sinergi Gula Nusantara,” SEJAGAT Jurnal Pengabdian Masyarakat, vol. 1, no. 2, pp. 56–63, 2024, doi: https://doi.org/10.25047/sejagat.v1i2.5219.

Rui Hong Teoh, Arya S. Mahajan, Sana R. Moharir, Norhuda Abdul Manaf, Suan Shi, Suchithra Thangalazy-Gopakumar, “A review on hydrothermal treatments for solid, liquid and gaseous fuel production from biomass,” Energy Nexus, vol. 14, July 2024, doi: https://doi.org/10.1016/j.nexus.2024.100301.

R. S. Harjanti, “Pupuk Organik dari Limbah Pabrik Gula Madukismo dengan Starter Mikrobia Pengurai Untuk Menambah Kandungan N, P, K,” Chem. J. Tek. Kim., vol. 4, no. 1, pp. 1–7, 2017, doi: https://doi.org/10.26555/chemica.v4i1.6107.

S. Dwi Anggraeni Susanti Purwadi, “Kualitas Vermikompos Limbah Blotong Tebu (Saccharum oficinarum L.) dengan Variasi Jenis Cacing,” J. BIOTEK, vol. 10, no. 2, p. 31673, 2022, doi: https://doi.org/10.24252/jb.v10i2.31673.

M. Ali and M. Mirwan, “Utilization of Blotong as an Activator Organic Fertilizer,” J. Community Serv., vol. 3, no. 2, pp. 152–161, 2021, doi: https://doi.org/10.56670/jcs.v3i2.103.

N.N. Safie, A. Y Zahrim, “Recovery of nutrients from sewage using zeolite-chitosan-biochar adsorbent: Current practices and perspectives,” J. of Water Process Engineering, vol. 40, 2021, doi: https://doi.org/10.1016/j.jwpe.2020.101845.

A. Wiyono et al., “Review on Synthesis Methods of Carbon Nanotubes as Activated Carbon Composites Based on Biomass for Supercapacitors in Electric Vehicles,” vol. 2401228, 2024, doi: https://doi.org/10.1002/ente.202401228.

Shima Masoumi, Venu Babu Borugadda, Sonil Nanda, Ajay K. Dalai, “Hydrochar: A Review on Its Production Technologies and Applications,” Catalysts., vol. 11 no. 8, 2021, doi: https://doi.org/10.3390/catal11080939.

P. V. V. Moreira, W. M. Moreira, D. F. dos Santos, H. Straioto, and M. F. Vieira, “Hydrothermal modification of natural zeolite and its application in anti-inflammatory removal,” J. Chem. Technol. Biotechnol., 2024, doi: https://doi.org/10.1002/jctb.7749.

A. Abidin, C. W. Purnomo, and R. B. Cahyono, “Hydro-char production from press-mud wastes of the sugarcane industry by hydrothermal treatment with natural zeolite addition,” AIP Conf. Proc., vol. 2026, 2018, doi: https://doi.org/10.1063/1.5065009.

S. Novianti, A. Nurdiawati, I. N. Zaini, P. Prawisudha, H. Sumida, and K. Yoshikawa, “Low-potassium Fuel Production from Empty Fruit Bunches by Hydrothermal Treatment Processing and Water Leaching,” Energy Procedia, vol. 75, pp. 584–589, 2015, doi: https://doi.org/10.1016/j.egypro.2015.07.460.

I. Leusbrock, S. J. Metz, G. Rexwinkel, and G. F. Versteeg, “Solubility of 1:1 alkali nitrates and cvhlorides in near-critical and supercritical weater,” J. Chem. Eng. Data, vol. 54, no. 12, pp. 3215 – 3223, 2009, doi: https://doi.org/10.1021/je900175b.

M. Ahmed, N. Fonseca Acosta, H. Garcia Hernandez, and C. Dupont, “Comprehensive assessment of cow manure hydrothermal treatment products for land application and energy recovery,” J. Environ. Manage., vol. 368, 2024, doi: https://doi.org/10.1016/j.jenvman.2024.122168.

E. Sulistyoningsih and S. Zahrina, “Kinetika Reaksi Pembuatan Kalium Sulfat dari Ekstrak Abu Batang Pisang dan Asam Sulfat,” vol. 8, no. 2, pp. 57–62, 2014.

P. Orosco and M. D. C. Ruiz, “Potassium chloride production by microcline chlorination,” Thermochim. Acta, vol. 613, pp. 108 – 112, 2015, doi: https://doi.org/10.1016/j.tca.2015.05.021.

A. R. Anwar, A. Ala, T. Kuswinanti, and E. Syam’un, “Effect of ashing temperature on potassium nutrient content of various organic matter,” in IOP Conference Series: Earth and Environmental Science, 2021, vol. 807, no. 4. doi: https://doi.org/10.1088/1755-1315/807/4/042044.

M. Mustaqim, C. W. Purnomo, and R. B. Cahyono, “Potassium recovery from banana peels by hydrothermal treatment,” in AIP Conference Proceedings, 2018, vol. 2026. doi: https://doi.org/10.1063/1.5065008.

J. Long, J. Ye, X. Song, L. Deng, and D. Che, “Transformation Characteristics of Potassium During Biomass Combustion,” Ranshao Kexue Yu Jishu/Journal Combust. Sci. Technol., vol. 24, no. 5, pp. 471 – 476, 2018, doi: 10.11715/rskxjs.R201804024.

H. Yuexin, L. Jie, and Y. Wanzhong, “Research on the mechanism of the dissociation of potassium shale during roasting,” Adv. Mater. Res., vol. 58, pp. 155 – 162, 2009, doi: https://doi.org/10.4028/www.scientific.net/AMR.58.155.

L. Sukeksi, R. D. Hidayati, and A. B. Paduana, “Leaching Kalium dari Abu Kulit Coklat (Theobroma cacao L.) Menggunakan Pelarut Air,” vol. 6, no. 2, pp. 30–34, 2017, doi: https://doi.org/10.32734/jtk.v6i2.1580.

J. Alves-Ferreira, L. C. Duarte, M. C. Fernandes, H. Pereira, and F. Carvalheiro, “Hydrothermal Treatments of Cistus ladanifer Industrial Residues Obtained from Essential Oil Distilleries,” Waste and Biomass Valorization, vol. 10, no. 5, pp. 1303 – 1310, 2019, doi: https://doi.org/10.1007/s12649-017-0127-3.

P. J. Arauzo, M. Lucian, L. Du, M. P. Olszewski, L. Fiori, and A. Kruse, “Improving the recovery of phenolic compounds from spent coffee grounds by using hydrothermal delignification coupled with ultrasound assisted extraction,” Biomass and Bioenergy, vol. 139, 2020, doi: https://doi.org/10.1016/j.biombioe.2020.105616.

Wei Meng, Lei Zheng, Changjun He, Shikun Cheng, Zifu Li, “Hydrothermal treatment of septic sludge: Revealing temperature-sensitive dissolved organic matter and potential toxicity relationships in the hydrothermal liquid,” Journal of Environmental Management, vol. 373, January 2025, doi: https://doi.org/10.1016/j.jenvman.2024.123550.

Cagri Un, “Enhancing Sewage Sludge Treatment with Hydrothermal Processing: A Case Study of Adana City,” Sustainability, vol. 16 no. 10, 2024, doi: https://doi.org/10.3390/su16104174.

Sabrina Summers, Qi Jing, Harshal Kawale, Zihan Wang, David Mirzaei, Yuanhui Zhang, “Waste Biorefinery Concept for Production of Value-Added Products Through Hydrothermal Liquefaction Pathway: A Critical Review and Outlook,” ACS EST Engg., September 23, 2025, doi: https://doi.org/10.1021/acsestengg.5c00273.

Lisa Axelsson, Maria Franzén, Madelene Ostwald, Göran Berndes, G. Lakshmi, N.H. Ravindranath, “Jatropha cultivation in southern India: assessing farmers' experiences,” Biofuels, Bioprod. Biorefining, vol. 6, no. 3, pp. 246–256, 2012, doi: https://doi.org/10.1002/bbb.1324.

S. Kumar, “Hydrothermal Treatment for Biofuels: Lignocellulosic Biomass to Bioethanol, Biocrude, and Biochar.” pp. 1–239, 2010.

Z. Shen, W. Zhang, X. Zeng, F. Jin, G. Yao, and Y. Wang, Water under high-temperature and high-pressure conditions and some special reactions under hydrothermal conditions. CRC Press, 2017. doi: https://doi.org/10.1201/9781351262842.

C. M. Comisar and P. E. Savage, “High-temperature water; specific or general acid/base catalyst?,” in AIChE Annual Meeting, Conference Proceedings, 2005.

H. M. Hussain and A. A. K. Mohammed, “Preparation and Characterization of mordenite Zeolite from Iraqi Sand,” in IOP Conference Series: Materials Science and Engineering, 2019, vol. 518, no. 6. doi: https://doi.org/10.1088/1757-899X/518/6/062002.

Y. H. Lee, W. Y. Kim, H. Park, Y. H. Choi, and J. S. Lee, “Highly Active and Coke-Tolerant Hierarchical Mordenite Catalysts Synthesized by Recrystallization for the Isopropylation of Naphthalene,” ChemCatChem, vol. 8, no. 18, pp. 2996 – 3001, 2016, doi: https://doi.org/10.1002/cctc.201600658.

H. M. Aly, M. E. Moustafa, and E. A. Abdelrahman, “Synthesis of mordenite zeolite in absence of organic template,” Adv. Powder Technol., vol. 23, no. 6, pp. 757 – 760, 2012, doi: https://doi.org/10.1016/j.apt.2011.10.003.

N. Gunadi, “Kalium Sulfat dan Kalium Klorida sebagai Sumber Pupuk Kalium pada Tanaman Bawang Merah,” J. Hortik., vol. 19, no. 192, pp. 174–185, 2009.

Jiazhong Zang, Haibin Yu, Guanfeng Liu, Meihua Hong, Jiawei Liu, Tiehong Chen, “Research Progress on Modifications of Zeolite Y for Improved Catalytic Properties,” Inorganics, vol. 11, no. 1, 2023, doi: https://doi.org/10.3390/inorganics11010022.

Jinxiao Sun, Xiaohan Wang, Qiang Wei, Yasong Zhou, “Synthesis of small crystal NiY zeolites and their catalytic performance in hydrocracking,” Journal of Fuel Chemistry and Technology, vol. 52, no. 6, pp. 775 – 789, 2024, doi: https://doi.org/10.1016/S1872-5813(24)60432-9.

Y. Zhang, Y. Li, J. Gu, S. Tian, and P. Ning, “Hydrothermal stability of different zeolites in supercritical water: Implication for synthesis of supported catalysts by supercritical water impregnation,” Korean J. Chem. Eng., vol. 35, no. 9, pp. 1932 – 1940, 2018, doi: https://doi.org/10.1007/s11814-018-0084-y.

Shiyu Liu, Qiuyun Huang, Ijaz Ul Haq, Zixu Yang, Weihua Shen, Yunjin Fang, “Direct conversion of syngas to aromatics via a two-stage C–C coupling over MnZr/HZSM-5 bifunctional catalysts employing OX-ZEO strategy,” Catalysis Science & Technology, no. 2, pp. 580 – 591, 2025, doi: https://doi.org/10.1039/D4CY01388C.

S. L. Aini, “Aktivasi Zeolit Alam dengan Perlakuan Hidrotermal Dan Karakterisasinya serta Uji Aktivitas Adsorpsi Air dalam Campuran Air-Etanol,” 2011.

Y. Hui et al., “Insight into the nature and the transformation of the hydroxyl species in the CeY zeolite,” Inorg. Chem. Front., vol. 9, no. 7, pp. 1354 – 1365, 2022, doi: https://doi.org/10.1039/D1QI01564H.

H. Nasution, H. Harahap, S. Pandia, D. M. Putra, and M. T. Al Fath, “Characterizations of activated zeolite using hydrolysis method,” in AIP Conference Proceedings, vol. 2175, 2019,doi: https://doi.org/10.1063/1.5134583.

Fadliah, Christin Palit, Reno Pratiwi, Reza Aryanto, Tri Widayati Putri, “Analysis the Effect of Activated Natural Zeolites for Fe Metal Adsorption,” Walisongo Journal of Chemistry, vol. 6 no. 2, 2023. doi: https://doi.org/10.21580/wjc.v6i2.17291.

M. Anshori, “Perengkahan Katalitik terhadap Minyak Hasil Pirolisis Plastik Ldpe (Low Density Polyehtylene) Menggunakan Katalis Cr-Zeolit,” 2017.

S. Sriatun, N. A. N. Qori’Ah, A. Suseno, S. Sriyanti, and A. Darmawan, “Effect of silica precursors on silica-alumina catalyst synthesis for hydrocracking reactions,” in AIP Conference Proceedings, vol. 3165, no. 1, 2024,doi: https://doi.org/10.1063/5.0216893.

Yuhang Ding, Huiyong Liu, Haitao Xue, Peinyuan Cong, Yinheng Zhao, Bing Xiang, Changyong Xia, “Improving the green mechanical strength and thermal shock resistance of colloidal silica-bonded castables using La2O3,” Int. Journal of Applied Ceramic Technology, vol. 21, no. 1, pp. 476 – 484, 2023, doi: https://doi.org/10.1111/ijac.14534.

M. Choiron and S. Tojo, “The Effect of Hot Compressed Water on Ion Released of a Wasted Biomass Treatment,” in AIP Conference Proceedings, 2023, vol. 2583. doi: https://doi.org/10.1063/5.0116208.

S. Yoshimoto, N. Luthfi, K. Nakano, T. Fukushima, and K. Takisawa, “Effects of potassium on hydrothermal carbonization of sorghum bagasse,” Bioresour. Bioprocess., vol. 10, no. 1, 2023, doi: https://doi.org/10.1186/s40643-023-00645-4.

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2025-10-07

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